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Cited 87 time in webofscience Cited 92 time in scopus
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dc.contributor.authorZhang, T-
dc.contributor.authorImanishi, N-
dc.contributor.authorShimonishi, Y-
dc.contributor.authorHirano, A-
dc.contributor.authorXie, J-
dc.contributor.authorTakeda, Y-
dc.contributor.authorYamamoto, O-
dc.contributor.authorSammes, N-
dc.date.accessioned2017-07-19T12:28:41Z-
dc.date.available2017-07-19T12:28:41Z-
dc.date.created2013-07-31-
dc.date.issued2010-01-
dc.identifier.issn0013-4651-
dc.identifier.urihttps://oasis.postech.ac.kr/handle/2014.oak/35881-
dc.description.abstractThe stability of water-stable lithium metal in aqueous acetic acid solution was examined as an anode in a lithium-air rechargeable battery. The water-stable lithium anode consisted of a water-stable glass-ceramic Li(1+x+y)Ti(2-x)Al(x)Si(y)P(3-y)O(12) (LTAP), a poly(ethylene oxide) (PEO)-based electrolyte with Li(CF(3)SO(2))(2)N (LiTFSI), and lithium metal. The LTAP immersed in CH(3)COOH (HAc)-H(2)O-saturated CH(3)COOLi (LiAc) solutions at 50 degrees C for several weeks showed no change in the X-ray diffraction pattern and showed a slight decrease in the electrical conductivity. The water-stable lithium anode, Li/PEO(18)LiTFSI/LTAP, showed a total resistance of 164 cm(2) at 60 degrees C after being immersed in HAc (90 vol %)-H(2)O (10 vol %)-saturated LiAc for 1 week. The Li/PEO(18)LiTFSI/LTAP/HAc-H(2)O-LiAc/Pt black air cell had a low polarization for lithium dissolution and deposition at a current density of 1 mA cm(-2). A prototype lithium-air cell using a carbon air electrode with a platinum catalyst showed a good charge and discharge cycle performance, and about 30% of acetic acid in the cell was consumed and recovered in the charge and discharge process.-
dc.languageEnglish-
dc.publisherELECTROCHEMICAL SOC INC-
dc.relation.isPartOfJOURNAL OF THE ELECTROCHEMICAL SOCIETY-
dc.titleStability of a Water-Stable Lithium Metal Anode for a Lithium-Air Battery with Acetic Acid-Water Solutions-
dc.typeArticle-
dc.identifier.doi10.1149/1.3271103-
dc.type.rimsART-
dc.identifier.bibliographicCitationJOURNAL OF THE ELECTROCHEMICAL SOCIETY, v.157, no.2, pp.A214 - A218-
dc.identifier.wosid000273222700015-
dc.date.tcdate2019-03-01-
dc.citation.endPageA218-
dc.citation.number2-
dc.citation.startPageA214-
dc.citation.titleJOURNAL OF THE ELECTROCHEMICAL SOCIETY-
dc.citation.volume157-
dc.contributor.affiliatedAuthorSammes, N-
dc.identifier.scopusid2-s2.0-73849137838-
dc.description.journalClass1-
dc.description.journalClass1-
dc.description.wostc77-
dc.description.scptc77*
dc.date.scptcdate2018-05-121*
dc.type.docTypeArticle-
dc.subject.keywordPlusSECONDARY BATTERIES-
dc.subject.keywordPlusGLASS-CERAMICS-
dc.subject.keywordPlusELECTROLYTE-
dc.subject.keywordPlusLI-
dc.subject.keywordPlusCOMPOSITE-
dc.subject.keywordAuthoranodes-
dc.subject.keywordAuthorcatalysts-
dc.subject.keywordAuthorcurrent density-
dc.subject.keywordAuthorelectrical conductivity-
dc.subject.keywordAuthorelectrolytes-
dc.subject.keywordAuthorglass ceramics-
dc.subject.keywordAuthorlithium compounds-
dc.subject.keywordAuthorsecondary cells-
dc.subject.keywordAuthorwater-
dc.subject.keywordAuthorX-ray diffraction-
dc.relation.journalWebOfScienceCategoryElectrochemistry-
dc.relation.journalWebOfScienceCategoryMaterials Science, Coatings & Films-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.relation.journalResearchAreaElectrochemistry-
dc.relation.journalResearchAreaMaterials Science-

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