Selective Glycerol Oxidation by Electrocatalytic Dehydrogenation
SCIE
SCOPUS
- Title
- Selective Glycerol Oxidation by Electrocatalytic Dehydrogenation
- Authors
- Hyung Ju Kim; JECHAN LEE; Sara K. Green; George W. Huber; Kim, WB
- Date Issued
- 2014-04
- Publisher
- Wiley
- Abstract
- This study demonstrates that an electrochemical dehydrogenation process can be used to oxidize glycerol to glyceraldehyde and glyceric acid even without using stoichiometric chemical oxidants. A glyceric acid selectivity of 87.0% at 91.8% glycerol conversion was obtained in an electrocatalytic batch reactor. A continuous-flow electrocatalytic reactor had over an 80% high glyceric acid selectivity at 10% glycerol conversion, as well as greater reaction rates than either an electrocatalytic or a conventional catalytic batch reactor.
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/37774
- DOI
- 10.1002/CSSC.201301218
- ISSN
- 1864-5631
- Article Type
- Article
- Citation
- ChemSusChem, vol. 7, no. 4, page. 1051 - 1056, 2014-04
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