DC Field | Value | Language |
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dc.contributor.author | Lee, S | - |
dc.contributor.author | Kim, H.J | - |
dc.contributor.author | E. J. lLim | - |
dc.contributor.author | Kim, Y | - |
dc.contributor.author | Noh, Y | - |
dc.contributor.author | George W. Huber | - |
dc.contributor.author | Kim, W.B. | - |
dc.date.accessioned | 2017-07-19T13:56:25Z | - |
dc.date.available | 2017-07-19T13:56:25Z | - |
dc.date.created | 2017-02-28 | - |
dc.date.issued | 2016-05 | - |
dc.identifier.issn | 1463-9262 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/37898 | - |
dc.description.abstract | We demonstrate an electrocatalytic reactor system for the partial oxidation of glycerol in an acidic solution to produce value-added chemicals, such as dihydroxyacetone (DHA), glyceraldehyde (GAD), glyceric acid (GLA), and glycolic acid (GCA). Under optimized conditions, the carbon-supported bimetallic PtSb (PtSb/C) catalyst was identified as a highly active catalyst for the selective oxidation of glycerol in the electrocatalytic reactor. The product selectivity can be strongly controlled as a function of the applied electrode potential and the catalyst surface composition. The main product from the electrocatalytic oxidation of glycerol was DHA, with a yield of 61.4% of DHA at a glycerol conversion of 90.3%, which can be achieved even without using any oxidants over the PtSb/C catalyst at 0.797 V (vs. SHE, standard hydrogen electrode). The electrocatalytic oxidation of biomass-derived glycerol represents a promising method of chemical transformation to produce value-added molecules. | - |
dc.language | English | - |
dc.publisher | Royal Society of Chemistry | - |
dc.relation.isPartOf | Green Chemistry | - |
dc.title | Highly Selective Transformation of Glycerol to Dihydroxyacetone without Using Oxidants by a PtSb/C-Catalyzed Electrooxidation Process | - |
dc.type | Article | - |
dc.identifier.doi | 10.1039/C5GC02865E | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | Green Chemistry, v.18, no.9, pp.2877 - 2887 | - |
dc.identifier.wosid | 000375291100038 | - |
dc.date.tcdate | 2019-02-01 | - |
dc.citation.endPage | 2887 | - |
dc.citation.number | 9 | - |
dc.citation.startPage | 2877 | - |
dc.citation.title | Green Chemistry | - |
dc.citation.volume | 18 | - |
dc.contributor.affiliatedAuthor | Kim, W.B. | - |
dc.identifier.scopusid | 2-s2.0-84966784644 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.wostc | 18 | - |
dc.description.scptc | 10 | * |
dc.date.scptcdate | 2018-05-121 | * |
dc.type.docType | Article | - |
dc.subject.keywordPlus | FREE AQUEOUS-SOLUTION | - |
dc.subject.keywordPlus | ELECTROCATALYTIC OXIDATION | - |
dc.subject.keywordPlus | LACTIC-ACID | - |
dc.subject.keywordPlus | PLATINUM | - |
dc.subject.keywordPlus | PD | - |
dc.subject.keywordPlus | BISMUTH | - |
dc.subject.keywordPlus | OXYGEN | - |
dc.subject.keywordPlus | AU | - |
dc.subject.keywordPlus | SPECTROSCOPY | - |
dc.subject.keywordPlus | ELECTRODES | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Green & Sustainable Science & Technology | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Science & Technology - Other Topics | - |
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