DC Field | Value | Language |
---|---|---|
dc.contributor.author | Jo, D | - |
dc.contributor.author | Lee, K | - |
dc.contributor.author | Park, GT | - |
dc.contributor.author | Hong, SB | - |
dc.date.accessioned | 2017-07-19T13:56:40Z | - |
dc.date.available | 2017-07-19T13:56:40Z | - |
dc.date.created | 2017-02-28 | - |
dc.date.issued | 2016-03 | - |
dc.identifier.issn | 0021-9517 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/37908 | - |
dc.description.abstract | We have investigated the effect of acid site density on the catalytic performance of high-silica (50 <= Si/Al <= 380) H-HPM-1 zeolite in the 1-butene skeletal isomerization. Changes (<= 0.5) in the number of framework Al atoms, and thus of Bronsted acid sites, per unit cell (60 tetrahedral atoms) led to striking variations in both 1-butene conversion and isobutene selectivity. Combining isobutene yield with catalyst durability, H-HPM-1 with a framework Si/Al ratio of 350 was found to perform better than any of the catalysts studied for this reaction thus far. (C) 2015 Elsevier Inc. All rights reserved. | - |
dc.language | English | - |
dc.publisher | ELSEVIER SCIENCE BV | - |
dc.relation.isPartOf | JOURNAL OF CATALYSIS | - |
dc.title | Acid site density effects in zeolite-catalyzed 1-butene skeletal isomerization | - |
dc.type | Article | - |
dc.identifier.doi | 10.1016/J.JCAT.2015.12.011 | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | JOURNAL OF CATALYSIS, v.335, pp.58 - 71 | - |
dc.identifier.wosid | 000371098200006 | - |
dc.date.tcdate | 2019-02-01 | - |
dc.citation.endPage | 71 | - |
dc.citation.startPage | 58 | - |
dc.citation.title | JOURNAL OF CATALYSIS | - |
dc.citation.volume | 335 | - |
dc.contributor.affiliatedAuthor | Hong, SB | - |
dc.identifier.scopusid | 2-s2.0-84954425695 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.wostc | 6 | - |
dc.description.scptc | 3 | * |
dc.date.scptcdate | 2018-05-121 | * |
dc.type.docType | Article | - |
dc.subject.keywordPlus | COKE DEPOSITS | - |
dc.subject.keywordPlus | N-BUTENES | - |
dc.subject.keywordPlus | FERRIERITE | - |
dc.subject.keywordPlus | DEACTIVATION | - |
dc.subject.keywordAuthor | Zeolite H-HPM-1 | - |
dc.subject.keywordAuthor | 1-Butene skeletal isomerization | - |
dc.subject.keywordAuthor | Bronsted acid site density | - |
dc.subject.keywordAuthor | Catalyst durability | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalWebOfScienceCategory | Engineering, Chemical | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Engineering | - |
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