Base-promoted, deborylative secondary alkylation of N-heteroaromatic N-oxides with internal gem-bis[(pinacolato)boryl]alkanes: a facile derivatization of 2,2′-bipyridyl analogues
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- Title
- Base-promoted, deborylative secondary alkylation of N-heteroaromatic N-oxides with internal gem-bis[(pinacolato)boryl]alkanes: a facile derivatization of 2,2′-bipyridyl analogues
- Authors
- Hwang, Chiwon; Jo, Woohyun; Seung Hwan Cho
- Date Issued
- 2017-07
- Publisher
- Royal Society of Chemistry
- Abstract
- A base-promoted, secondary alkylation of N-heteroaromatic N-oxides using internal gem -bis[(pinacolato)boryl] alkanes as alkylation reagents is reported. The reaction exhibits a broad scope, providing deoxygenated secondary alkylated N-heteroaromatic compounds with high efficiency. The usefulness of the developed protocol is evidenced by the sequential direct alkylation of 2,2'-bipyridine-N-oxide.
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/39065
- DOI
- 10.1039/C7CC03731G
- ISSN
- 1359-7345
- Article Type
- Article
- Citation
- Chemical Communications, vol. 54, no. 54, page. 7573 - 7576, 2017-07
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- There are no files associated with this item.
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