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Zinc-Mediated syn-Selective Crotylation of N-Unsubstituted Imines SCIE SCOPUS
- Title
- Zinc-Mediated syn-Selective Crotylation of N-Unsubstituted Imines
- Authors
- Lee, W.J.; Jeong, W.; Park, J.; Rhee, Y.H.
- Date Issued
- 2017-04
- Publisher
- Wiley
- Abstract
- The first example of a zinc-mediated diastereoselective crotylation of N-unsubstititued imines is described. The use of Et3B as an additive was of crucial importance to achieve high yield and diastereoselectivity. Notably, a high level of syn-selectivity was observed. A mechanism involving an open transition state is suggested to explain this unique selectivity. ? 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
- ISSN
- 2193-5807
- Article Type
- Article
- Citation
- Asian Journal of Organic Chemistry, vol. 6, no. 4, page. 441 - 444, 2017-04
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