Synthesis of high-purity, layered structured K2Ta4O11 intermediate phase nanocrystals for photocatalytic water splitting

Abstract

High-purity K2Ta4O11 (kalitantite) intermediate phase with a layered structure, as a new family member of alkali-metal tantalate semiconductors, was successfully prepared via a simple and cost-effective flux growth technique using potassium chloride (KCl) at a low temperature of 800 degrees C for only 4 h. The as-synthesized K2Ta4O11 was characterized by XRD, SEM, TEM, STEM/EDS, and UV-Vis DRS, etc. It was found that the K2Ta4O11 single nanocrystals were non-stoichiometric in the size range of 100-500 nm, and the indirect band gap of K2Ta4O11 was correctly determined to be 4.15 eV. The K2Ta4O11 not only exhibited a high and stable photocatalytic H-2 generation rate of B45.3 mu mol h(-1) g(-1) in an aqueous methanolic solution with the photodeposition of Pt as co-catalysts, but also possessed the photocatalytic ability for simultaneous evolution of H-2 and O-2 in a stoichiometric ratio, with loading of NiO particles as cocatalysts. Thus, it can be mainly attributed to the benefits of KCl flux lowing the reaction temperature, and increasing the surface area and crystallinity of K2Ta4O11, that the charge efficiency and enhancement of the photoreactivity for water splitting are improved.