DC Field | Value | Language |
---|---|---|
dc.contributor.author | Nguyen, LTM | - |
dc.contributor.author | Park, H | - |
dc.contributor.author | Banu, M | - |
dc.contributor.author | Kim, JY | - |
dc.contributor.author | Youn, DH | - |
dc.contributor.author | Magesh, G | - |
dc.contributor.author | Kim, WY | - |
dc.contributor.author | Lee, JS | - |
dc.date.accessioned | 2018-10-04T05:50:35Z | - |
dc.date.available | 2018-10-04T05:50:35Z | - |
dc.date.created | 2016-11-23 | - |
dc.date.issued | 2015-12 | - |
dc.identifier.issn | 2046-2069 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/92351 | - |
dc.description.abstract | Pure formic acid was successfully produced via CO2 hydrogenation for the first time over a heterogeneous catalyst of PdNi alloy on a carbon nanotube-graphene (CNT-GR) support in water as an eco-friendly solvent without a base additive. The highest formic acid yield obtained was 1.92 mmol with a turnover number of 6.4 and a turnover frequency of 1.2 x 10(-4) s(-1) under mild reaction conditions of 40 degrees C and 50 bar. Alloying Pd with Ni brought a significant enhancement in catalytic activity compared to the monometallic Pd catalyst. In addition, the CNT-GR composite as a catalytic support improved the dispersion of Pd-Ni alloy particles, which exhibited good stability under the reaction conditions. | - |
dc.language | English | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.relation.isPartOf | RSC ADVANCES | - |
dc.subject | FISCHER-TROPSCH SYNTHESIS | - |
dc.subject | ROOM-TEMPERATURE | - |
dc.subject | PALLADIUM NANOPARTICLES | - |
dc.subject | AQUA COMPLEXES | - |
dc.subject | DIOXIDE | - |
dc.subject | DECOMPOSITION | - |
dc.subject | STORAGE | - |
dc.subject | NANOCATALYST | - |
dc.subject | BICARBONATE | - |
dc.subject | REDUCTION | - |
dc.title | Catalytic CO2 hydrogenation to formic acid over carbon nanotube-graphene supported PdNi alloy catalysts | - |
dc.type | Article | - |
dc.identifier.doi | 10.1039/c5ra21017h | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | RSC ADVANCES, v.5, no.128, pp.105560 - 105566 | - |
dc.identifier.wosid | 000366965200007 | - |
dc.date.tcdate | 2019-02-01 | - |
dc.citation.endPage | 105566 | - |
dc.citation.number | 128 | - |
dc.citation.startPage | 105560 | - |
dc.citation.title | RSC ADVANCES | - |
dc.citation.volume | 5 | - |
dc.contributor.affiliatedAuthor | Park, H | - |
dc.contributor.affiliatedAuthor | Kim, WY | - |
dc.identifier.scopusid | 2-s2.0-84950336405 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.wostc | 26 | - |
dc.type.docType | Article | - |
dc.subject.keywordPlus | FISCHER-TROPSCH SYNTHESIS | - |
dc.subject.keywordPlus | ROOM-TEMPERATURE | - |
dc.subject.keywordPlus | PALLADIUM NANOPARTICLES | - |
dc.subject.keywordPlus | AQUA COMPLEXES | - |
dc.subject.keywordPlus | DIOXIDE | - |
dc.subject.keywordPlus | DECOMPOSITION | - |
dc.subject.keywordPlus | STORAGE | - |
dc.subject.keywordPlus | NANOCATALYST | - |
dc.subject.keywordPlus | BICARBONATE | - |
dc.subject.keywordPlus | REDUCTION | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
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