DC Field | Value | Language |
---|---|---|
dc.contributor.author | Smith, Peter T. | - |
dc.contributor.author | Benke, Bahiru Punja | - |
dc.contributor.author | Cao, Zhi | - |
dc.contributor.author | Kim, Younghoon | - |
dc.contributor.author | Nichols, Eva M. | - |
dc.contributor.author | Kim, Kimoon | - |
dc.contributor.author | Chang, Christopher J. | - |
dc.date.accessioned | 2019-04-07T16:56:43Z | - |
dc.date.available | 2019-04-07T16:56:43Z | - |
dc.date.created | 2018-08-16 | - |
dc.date.issued | 2018-07 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/95728 | - |
dc.description.abstract | A porous organic cage composed of six iron tetraphenylporphyrins was used as a supramolecular catalyst for electrochemical CO2-to-CO conversion. This strategy enhances active site exposure and substrate diffusion relative to the monomeric catalyst, resulting in CO generation with near-quantitative Faradaic efficiency in pH7.3 water, with activities reaching 55250 turnovers. These results provide a starting point for the design of supramolecular catalysts that can exploit the properties of the surrounding matrix yet retain the tunability of the original molecular unit. | - |
dc.language | English | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.relation.isPartOf | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | - |
dc.title | Iron Porphyrins Embedded into a Supramolecular Porous Organic Cage for Electrochemical CO2 Reduction in Water | - |
dc.type | Article | - |
dc.identifier.doi | 10.1002/anie.201803873 | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.57, no.31, pp.9684 - 9688 | - |
dc.identifier.wosid | 000439741900014 | - |
dc.citation.endPage | 9688 | - |
dc.citation.number | 31 | - |
dc.citation.startPage | 9684 | - |
dc.citation.title | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | - |
dc.citation.volume | 57 | - |
dc.contributor.affiliatedAuthor | Kim, Kimoon | - |
dc.identifier.scopusid | 2-s2.0-85050454472 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.type.docType | Article | - |
dc.subject.keywordPlus | CARBON-DIOXIDE REDUCTION | - |
dc.subject.keywordPlus | CO2-TO-CO CONVERSION | - |
dc.subject.keywordPlus | MOLECULAR CATALYSIS | - |
dc.subject.keywordPlus | COBALT PORPHYRIN | - |
dc.subject.keywordPlus | EFFICIENT | - |
dc.subject.keywordPlus | ELECTROREDUCTION | - |
dc.subject.keywordPlus | IMMOBILIZATION | - |
dc.subject.keywordPlus | SELECTIVITY | - |
dc.subject.keywordPlus | ELECTROCATALYSTS | - |
dc.subject.keywordPlus | ELECTRODES | - |
dc.subject.keywordAuthor | CO2 reduction | - |
dc.subject.keywordAuthor | electrochemistry | - |
dc.subject.keywordAuthor | porous organic cages | - |
dc.subject.keywordAuthor | porphyrins | - |
dc.subject.keywordAuthor | supramolecular chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
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