Dopant dependent band gap tailoring of hydrothermally prepared cubic SrTixM1-xO3 (M=Ru,Rh,Ir,Pt,Pd) nanoparticles as visible light photocatalysts
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- Title
- Dopant dependent band gap tailoring of hydrothermally prepared cubic SrTixM1-xO3 (M=Ru,Rh,Ir,Pt,Pd) nanoparticles as visible light photocatalysts
- Authors
- Bae, SW; Borse, PH; Lee, JS
- Date Issued
- 2008-03-10
- Publisher
- AMER INST PHYSICS
- Abstract
- Nanostructured cubic SrTiO3 particles were hydrothermally synthesized and studied experimentally/theoretically for photoreduction of water. The particles were doped with metal atoms (M=Ru,Rh,Ir,Pt,Pd), which acquired high cyrstallinity after thermal treatment. SrTiO3:Rh showed the highest rate of H-2 evolution under lambda>420 nm photons. The density functional theory calculations of SrTixM1-xO3 (M=Ru,Rh,Ir,Pt) implied that the photocatalytic activity of SrTixRh1-xO3 was due to its suitable band energetics, and the induced hybridized Ti/Rh orbitals in the bandgap of SrTiO3. (C) 2008 American Institute of Physics.
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/9639
- DOI
- 10.1063/1.2897300
- ISSN
- 0003-6951
- Article Type
- Article
- Citation
- APPLIED PHYSICS LETTERS, vol. 92, no. 10, 2008-03-10
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