DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kim, HJ | - |
dc.contributor.author | Jung, S | - |
dc.contributor.author | Jeon, YM | - |
dc.contributor.author | Whang, D | - |
dc.contributor.author | Kim, K | - |
dc.date.accessioned | 2015-06-25T01:35:54Z | - |
dc.date.available | 2015-06-25T01:35:54Z | - |
dc.date.created | 2009-03-20 | - |
dc.date.issued | 1997-11-21 | - |
dc.identifier.issn | 1359-7345 | - |
dc.identifier.other | 2015-OAK-0000009987 | en_US |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/9873 | - |
dc.description.abstract | Reactions of (por)ZrCl2 [por = octaethylporphyrinato (oep) or tetraphenylporphyrinato (tpp) dianion] with TlCp and diphenylacetylene in the presence of Na/Hg or Mg produce novel low-valent zirconium porphyrin complexes (por)Zr(eta(5)-Cp) 1 and (por)Zr(eta(2)-PhC=CPh) 2, respectively; spectroscopic and/or structural data for 1 and 2 are consistent with a formalism in which 1 is a resonance hybrid of a zirconium(III) metal-centered radical and a zirconium(IV) porphyrin radical anion while 2 is a zirconium(II) complex stabilized by a four-electron-donor alkyne ligand. | - |
dc.description.statementofresponsibility | open | en_US |
dc.language | English | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.relation.isPartOf | CHEMICAL COMMUNICATIONS | - |
dc.rights | BY_NC_ND | en_US |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/2.0/kr | en_US |
dc.title | Novel low-valent zirconium porphyrin complexes: syntheses, characterization and x-ray crystal structures of (eta(5)-cyclopentadienyl)zirconium tetraphenylporphyrin and (eta(2)-diphenylacetylene)zirconium octaethylporphyrin | - |
dc.type | Article | - |
dc.contributor.college | 화학과 | en_US |
dc.identifier.doi | 10.1039/a705181f | - |
dc.author.google | Kim, HJ | en_US |
dc.author.google | Jung, S | en_US |
dc.author.google | Kim, K | en_US |
dc.author.google | Whang, D | en_US |
dc.author.google | Jeon, YM | en_US |
dc.relation.issue | 22 | en_US |
dc.relation.startpage | 2201 | en_US |
dc.relation.lastpage | 2202 | en_US |
dc.contributor.id | 10104366 | en_US |
dc.relation.journal | CHEMICAL COMMUNICATIONS | en_US |
dc.relation.index | SCI급, SCOPUS 등재논문 | en_US |
dc.relation.sci | SCI | en_US |
dc.collections.name | Journal Papers | en_US |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | CHEMICAL COMMUNICATIONS, no.22, pp.2201 - 2202 | - |
dc.identifier.wosid | A1997YG75800035 | - |
dc.date.tcdate | 2019-01-01 | - |
dc.citation.endPage | 2202 | - |
dc.citation.number | 22 | - |
dc.citation.startPage | 2201 | - |
dc.citation.title | CHEMICAL COMMUNICATIONS | - |
dc.contributor.affiliatedAuthor | Kim, K | - |
dc.identifier.scopusid | 2-s2.0-0007957742 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.wostc | 13 | - |
dc.type.docType | Article | - |
dc.subject.keywordPlus | TRANSITION-METAL PORPHYRINS | - |
dc.subject.keywordPlus | ZIRCONOCENE COMPLEXES | - |
dc.subject.keywordPlus | PROMOTED CYCLIZATION | - |
dc.subject.keywordPlus | SANDWICH COMPOUND | - |
dc.subject.keywordPlus | DERIVATIVES | - |
dc.subject.keywordPlus | BICYCLIZATION | - |
dc.subject.keywordPlus | REACTIVITY | - |
dc.subject.keywordPlus | ALKYNES | - |
dc.subject.keywordPlus | LIGANDS | - |
dc.subject.keywordPlus | DIALKYL | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
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