DC Field | Value | Language |
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dc.contributor.author | HAN, SEUNGCHEOL | - |
dc.contributor.author | LEE, YEOSAN | - |
dc.contributor.author | YUJIN, JUNGYUJIN | - |
dc.contributor.author | CHO, SEUNG HWAN | - |
dc.date.accessioned | 2022-09-06T06:20:18Z | - |
dc.date.available | 2022-09-06T06:20:18Z | - |
dc.date.created | 2022-08-30 | - |
dc.date.issued | 2022-08 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/113655 | - |
dc.description.abstract | Reported herein is the efficient synthesis of tetra- and tri-substituted ( Z )-fluoro- and ( Z )-chloro-borylalkenes by the Boron–Wittig reaction of ketones and aldehydes with bench-top stable halo-diborylmethanes. The substrate scope is broad and the Boron–Wittig reaction proceeds from a diverse range of ketones and aldehydes including biologically relevant molecules with fluoro- or chloro-diborylmethanes, providing tetra- and tri-substituted ( Z )-fluoro- and ( Z )-chloro-borylalkenes in good yields with high stereoselectivity. The utilities of the obtained ( Z )-fluoro- and ( Z )-chloro-borylalkenes are highlighted by further modifications to afford fluoroalkene derivatives or all-carbon substituted alkene. | - |
dc.language | English | - |
dc.publisher | John Wiley & Sons Ltd. | - |
dc.relation.isPartOf | Angewandte Chemie - International Edition | - |
dc.title | Stereoselective Access to Tetra‐ and Tri‐Substituted Fluoro‐ and Chloro‐borylalkenes via Boron‐Wittig Reaction | - |
dc.type | Article | - |
dc.identifier.doi | 10.1002/anie.202210532 | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | Angewandte Chemie - International Edition, v.61, no.41 | - |
dc.identifier.wosid | 000850313800001 | - |
dc.citation.number | 41 | - |
dc.citation.title | Angewandte Chemie - International Edition | - |
dc.citation.volume | 61 | - |
dc.contributor.affiliatedAuthor | HAN, SEUNGCHEOL | - |
dc.contributor.affiliatedAuthor | LEE, YEOSAN | - |
dc.contributor.affiliatedAuthor | YUJIN, JUNGYUJIN | - |
dc.contributor.affiliatedAuthor | CHO, SEUNG HWAN | - |
dc.identifier.scopusid | 2-s2.0-85138404739 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.type.docType | Article; Early Access | - |
dc.subject.keywordPlus | TETRASUBSTITUTED GEM-DIFLUOROALKENES | - |
dc.subject.keywordPlus | DIPEPTIDE ISOSTERES | - |
dc.subject.keywordPlus | CARBONYL-COMPOUNDS | - |
dc.subject.keywordPlus | HECK REACTION | - |
dc.subject.keywordPlus | ALDEHYDES | - |
dc.subject.keywordPlus | KETONES | - |
dc.subject.keywordPlus | CARBANIONS | - |
dc.subject.keywordPlus | HALIDES | - |
dc.subject.keywordPlus | BIS(ETHYLENEDIOXYBORYL)METHIDE | - |
dc.subject.keywordPlus | HYDRODEFLUORINATION | - |
dc.subject.keywordAuthor | Boron | - |
dc.subject.keywordAuthor | Boron-Wittig Reaction | - |
dc.subject.keywordAuthor | Fluorine | - |
dc.subject.keywordAuthor | Halo-Borylalkene | - |
dc.subject.keywordAuthor | Stereoselectivity | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
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